Effects of three orthodontic retainers on periodontal pathogens and periodontal parameters.

The objective of this study was to compare and evaluate the changes in periodontal pathogens and periodontal status within 6 months of wearing three orthodontic retainers, namely, vacuum-formed retainer (VFR), Hawley retainer (HR), and lingual fixed retainer (LR). In total, 48 patients who underwent orthodontic treatment with ordinary metal brackets were divided into VFR, HR, and LR groups (n = 16 per group). Saliva samples were collected at the time of debonding (T0) and after 1 month (T1), 3 months (T2), and 6 months (T3). Porphyromonas gingivalis (Pg) and Aggregatibacter actinomycetemcomitans (Aa) were quantitatively analyzed using real-time PCR. Gingival index (GI), plaque index (PLI), and probing depth (PD) were measured at the four time points to evaluate changes in periodontal state. SPSS20.0 software was used to analyze the data, and P < 0.05 was considered statistically significant. The trial was registered at the Chinese Clinical Trial Registry (ChiCTR2300073704), the registration was retrospective. Compared to baseline (T0) values, Pg, Aa, GI, PLI, and PD were significantly decreased in all three groups 1 month after wearing the retainer (p < 0.05). Significant differences were observed in Aa at T3 among the three groups, whereby the HR group exhibited significantly better results compared to the VFR and LR groups (p < 0.05). Differences were found among the three groups' Porphyromonas gingivalis at T3, and the HR group was significantly better than the VFR and LR groups (P < 0.05). From T1 to T2, GI, PLI, and PD of the three groups tended to be stable, however differences were observed at T3, with the PLI and PD of the HR group being the lowest among the three groups (p < 0.05). Regardless of the type of retainer used, the periodontal condition of patients was significantly improved after removal of the metal brackets. After 6 months of retainer use, the Hawley retainer was superior to vacuum-formed retainer and lingual fixed retainer with regard to Pg, Aa, and periodontal clinical parameters.

3D microscopy at the nanoscale reveals unexpected lattice rotations in deformed nickel.

In polycrystalline metals, plastic deformation is accompanied by lattice rotations resulting from dislocation glide. Following these rotations in three dimensions requires nondestructive methods that so far have been limited to grain sizes at the micrometer scale. We tracked the rotations of individual grains in nanograined nickel by using three-dimensional orientation mapping in a transmission electron microscope before and after in situ nanomechanical testing. Many of the larger-size grains underwent unexpected lattice rotations, which we attributed to a reversal of rotation during unloading. This inherent reversible rotation originated from a back stress-driven dislocation slip process that was more active for larger grains. These results provide insights into the fundamental deformation mechanisms of nanograined metals and will help to guide strategies for material design and engineering applications.

Physiological cold tolerance evolves faster than climatic niches in plants.

Understanding how plants respond to thermal stress is central to predicting plant responses and community dynamics in natural ecosystems under projected scenarios of climate change. Although physiological tolerance is suggested to evolve slower than climatic niches, this comparison remains to be addressed in plants using a phylogenetic comparative approach. In this study, we compared i) the evolutionary rates of physiological tolerance to extreme temperatures with ii) the corresponding rates of climatic niche across three major vascular plant groups. We further accounted for the potential effects of hardening when examining the association between physiological and climatic niche rates. We found that physiological cold tolerance evolves faster than heat tolerance in all three groups. The coldest climatic-niche temperatures evolve faster than the warmest climatic-niche temperatures. Importantly, evolutionary rates of physiological cold tolerance were faster than rates of change in climatic niches. However, an inverse association between physiological cold tolerance and responding climatic niche for plants without hardening was detected. Our results indicated that plants may be sensitive to changes in warmer temperatures due to the slower evolutionary rates of heat tolerance. This pattern has deep implications for the framework that is being used to estimate climate-related extinctions over the upcoming century.

Twenty-four-hour ambulatory blood pressure variability and association with ischemic stroke subtypes in the subacute stage.

Background and purpose: Blood pressure (BP) variability (BPV) increases the risk of cerebral disease in both hemorrhagic and ischemic strokes. However, whether BPV is associated with different types of ischemic stroke remains unclear. In this study, we explored the relationship between BPV and ischemic stroke subtypes. Methods: We enrolled consecutive patients aged 47-95 years with ischemic stroke in the subacute stage. We categorized them into four groups based on their artery atherosclerosis severity, brain magnetic resonance imaging markers, and disease history: large-artery atherosclerosis, branch atheromatous disease, small-vessel disease, and cardioembolic stroke. Twenty-four-hour ambulatory blood pressure monitoring was performed, and the mean systolic blood pressure/diastolic blood pressure, standard deviation, and coefficient of variation were calculated. A multiple logistic regression model and random forest were used to test the relationship between BP and BPV in the different types of ischemic stroke. Results: A total of 286 patients, including 150 men (73.0 ± 12.3 years) and 136 women (77.8 ± 9.6 years) were included in the study. Of these, 86 (30.1%) patients had large-artery atherosclerosis, 76 (26.6%) had branch atheromatous disease, 82 (28.7%) had small-vessel disease, and 42 (14.7%) had cardioembolic stroke. There were statistically significant differences in BPV between subtypes of ischemic stroke in 24-h ambulatory blood pressure monitoring. The random forest model showed that BP and BPV were important features associated with ischemic stroke. Multinomial logistic regression analysis demonstrated that systolic blood pressure levels; systolic blood pressure variability at 24 h, daytime and nighttime; and nighttime diastolic blood pressure were independent risk factors for large-artery atherosclerosis after adjustment for confounders. When compared to branch atheromatous disease and small-vessel disease, nighttime diastolic blood pressure and standard deviation of diastolic blood pressure were significantly associated with patients in the cardioembolic stroke group. However, a similar statistical difference was not seen in patients with large-artery atherosclerosis. Conclusion: The results of this study indicate a discrepancy in blood pressure variability among different ischemic stroke subtypes during the subacute stage. Higher systolic blood pressure and systolic blood pressure variability during the 24 h, daytime, and nighttime, and nighttime diastolic blood pressure were independent predictors for large-artery atherosclerosis stroke. Increased nighttime diastolic BPV was an independent risk factor for cardioembolic stroke.

Multi-Scale Microstructural Tailoring and Associated Properties of Press-Hardened Steels: A Review.

High-strength press-hardened steels (PHS) are highly desired in the automotive industry to meet the requirement of carbon neutrality. This review aims to provide a systematic study of the relationship between multi-scale microstructural tailoring and the mechanical behavior and other service performance of PHS. It begins with a brief introduction to the background of PHS, followed by an in-depth description of the strategies used to enhance their properties. These strategies are categorized into traditional Mn-B steels and novel PHS. For traditional Mn-B steels, extensive research has verified that the addition of microalloying elements can refine the microstructure of PHS, resulting in improved mechanical properties, hydrogen embrittlement resistance, and other service performance. In the case of novel PHS, recent progress has principally demonstrated that the novel composition of steels coupling with innovative thermomechanical processing can obtain multi-phase structure and superior mechanical properties compared with traditional Mn-B steels, and their effect on oxidation resistance is highlighted. Finally, the review offers an outlook on the future development of PHS from the perspective of academic research and industrial applications.

In Situ Electrospinning of "Dry-Wet" Conversion Nanofiber Dressings for Wound Healing.

Rapid wound dressings provide an excellent solution strategy for the treatment of wounds in emergency situations. In this study, aqueous solvent-based PVA/SF/SA/GelMA nanofiber dressings fabricated by a handheld electrospinning device could deposit quickly and directly on the wound, perfectly fitting wounds with various sizes. Using an aqueous solvent overcame the disadvantage of using the current organic solvents as the medium for rapid wound dressings. The porous dressings had excellent air permeability to ensure smooth gas exchange at the wound site. The distribution range of the tensile strength of the dressings was 9-12 Kpa, and the tensile strain was between 60-80%, providing sufficient mechanical support during wound healing. The dressings could absorb 4-8 times their own weight in solution and could rapidly absorb wound exudates from wet wounds. The nanofibers formed ionic crosslinked hydrogel after absorbing exudates, maintaining the moist condition. It formed a hydrogel-nanofiber composite structure with un-gelled nanofibers and combined the photocrosslinking network to maintain a stable structure at the wound location. The in vitro cell culture assay indicated that the dressings had excellent cell cytocompatibility, and the addition of SF contributed to cell proliferation and wound healing. The in situ deposited nanofiber dressings had excellent potential in the urgent treatment of emergency wounds.

The Characteristic Microstructures and Properties of Steel-Based Alloy via Additive Manufacturing.

Differing from metal alloys produced by conventional techniques, metallic products prepared by additive manufacturing experience distinct solidification thermal histories and solid-state phase transformation processes, resulting in unique microstructures and superior performance. This review starts with commonly used additive manufacturing techniques in steel-based alloy and then some typical microstructures produced by metal additive manufacturing technologies with different components and processes are summarized, including porosity, dislocation cells, dendrite structures, residual stress, element segregation, etc. The characteristic microstructures may exert a significant influence on the properties of additively manufactured products, and thus it is important to tune the components and additive manufacturing process parameters to achieve the desired microstructures. Finally, the future development and prospects of additive manufacturing technology in steel are discussed.

Study on Corrosion Behavior and Mechanism of Ultrahigh-Strength Hot-Stamping Steel Based on Traditional and Compact Strip-Production Processes.

Hot-stamping steel is a type of high-strength steel that is mainly used in key safety components such as the front and rear bumpers, A-pillars, and B-pillars of vehicles. There are two methods of producing hot-stamping steel, i.e., the traditional process and the near net shape of compact strip production (CSP) process. To assess the potential risks of producing hot-stamping steel using CSP, the microstructure and mechanical properties, and especially the corrosion behavior were focused on between the traditional and CSP processes. The original microstructure of hot-stamping steel produced by the traditional process and the CSP process is different. After quenching, the microstructures transform into full martensite, and their mechanical properties meet the 1500 MPa grade. Corrosion tests showed that the faster the quenching speeds, the smaller the corrosion rate of the steel. The corrosion current density changes from 15 to 8.6 µA·cm-2. The corrosion resistance of hot-stamping steel produced by the CSP process is slightly better than that of traditional processes, mainly since the inclusion size and distribution density of CSP-produced steel were both smaller than those of the traditional process. The reduction of inclusions reduces the number of corrosion sites and improves the corrosion resistance of steel.

Phase Transformation Behaviors of Medium Carbon Steels Produced by Twin Roll Casting and Compact Strip Production Processes.

Medium carbon steels have been widely used in the fields of tool and die manufacturing due to their outstanding hardness and wear resistance. In this study, microstructures of 50# steel strips fabricated by twin roll casting (TRC) and compact strip production (CSP) processes were analyzed to investigate the influences of solidification cooling rate, rolling reduction, and coiling temperature on composition segregation, decarburization, and pearlitic phase transformation. The results show that a partial decarburization layer with a thickness of 13.3 µm and banded C-Mn segregation were observed in the 50# steel produced by CSP, leading to the banded distributions of ferrite and pearlite in the C-Mn poor regions and C-Mn rich regions, respectively. For the steel fabricated by TRC, owing to the sub-rapid solidification cooling rate and short processing time at high temperatures, neither apparent C-Mn segregation nor decarburization was observed. In addition, the steel strip fabricated by TRC has higher pearlite volume fractions, larger pearlite nodule sizes, smaller pearlite colony sizes and interlamellar spacings due to the co-influence of larger prior austenite grain size and lower coiling temperatures. The alleviated segregation, eliminated decarburization and large volume fraction of pearlite render TRC a promising process for medium carbon steel production.

The origins of climate-diversity relationships and richness patterns in Chinese plants.

A major goal of ecology and evolutionary biology is to explain geographic patterns of species richness. Richness is often correlated with climatic variables. However, the processes underlying these climate-diversity relationships remain poorly understood. Two potential hypotheses to explain these relationships involve: (i) faster diversification rates (speciation minus extinction) in high-richness climates and (ii) earlier colonization of high-richness climates, allowing more time for speciation to build up richness. Few studies have tested these hypotheses directly, and most focused on animal clades with limited richness. In this study, we test these hypotheses in Chinese angiosperms, encompassing ~10% of Earth's plant species, using large-scale phylogenetic, climatic, and distributional data including 26,977 species. We find that climatic zones that were colonized earlier have higher species richness. By contrast, relationships between diversification rates and richness of climatic zones are often nonsignificant or negative. Our study reveals that even when richness is strongly correlated with climate, the underlying explanation may still be rooted in phylogenetic history. Thus, climate may not be a competing explanation for richness patterns relative to colonization times and diversification rates. We also show that the timing of colonization can be crucial for explaining richness patterns. Yet, many recent studies have ignored this explanation and instead have focused solely on rates of speciation and diversification as drivers of diversity gradients.

Effect of the Severe Plastic Deformation on the Corrosion Resistance of a Tantalum-Tungsten Alloy.

Tantalum and its alloys are regarded as equipment construction materials for processing aggressive acidic media due to their excellent properties. In this study, the influence of severe rolling (90%) on the dissolution rate of a cold-rolled Ta-4%W sheet in different directions was investigated during immersion testing and the corresponding mechanism was discussed. The results show that the dissolution rate of the cold-rolled sample is significantly lower than that of the undeformed sample. The corrosion resistance followed the sequence of "initial" < "90%-ND" < "90%-RD" < "90%-TD", while the strength is in positive correlation with the corrosion resistance. Severe rolling promotes grain subdivision accompanied by long geometrically necessary boundaries and short incidental dislocation boundaries on two scales in the cold-rolled sample. The volume elements enclosed by geometrically necessary boundaries form preferential crystallographic orientations. Such preferential crystallographic orientations can greatly weaken the electrochemical process caused by adjacent volume elements, resulting in greatly reduced corrosion rates in the severely deformed sample. The unexpected finding provides a new idea for tailoring the structures of tantalum alloys to improve both their strength and corrosion resistance.

Canopy nitrogen addition enhance the photosynthetic rate of canopy species by improving leaf hydraulic conductivity in a subtropical forest.

Elucidating the effects of atmospheric nitrogen (N) deposition on the photosynthetic capacity of plants is critical to understand forest growth and conservation under global change. However, studies on this topic generally consider only understory N addition, which ignores the effect of canopy interception. In this study, we conducted a field experiment in a subtropical forest to compare the effects of canopy vs. understory N addition on the photosynthetic rate of canopy and understory species. We found that canopy N addition enhanced the photosynthetic rate of canopy species by increasing leaf hydraulic conductivity and shortening the distance of CO2 transportation. In contrast, understory N addition had non-significant effects on the photosynthetic rate of canopy species. Moreover, the photosynthetic rate of understory species was not affected by canopy or understory N addition. Interestingly, changes in hydraulic conductivity contributed more to accelerating the photosynthetic rate than changes in CO2 transport distance. Our results provide important insights into the dissimilar effects of canopy and understory N addition on the photosynthetic rates of species in subtropical forests. Based on our findings, we highlighted the urgent need to consider canopy processes in future studies on N deposition.

Prediction of Hardenability Curves for Non-Boron Steels via a Combined Machine Learning Model.

Hardenability is one of the most basic criteria influencing the formulation of the heat treatment process and steel selection. Therefore, it is of great engineering value to calculate the hardenability curves rapidly and accurately without resorting to any laborious and costly experiments. However, generating a high-precision computational model for steels with different hardenability remains a challenge. In this study, a combined machine learning (CML) model including k-nearest neighbor and random forest is established to predict the hardenability curves of non-boron steels solely on the basis of chemical compositions: (i) random forest is first applied to classify steel into low- and high-hardenability steel; (ii) k-nearest neighbor and random forest models are then developed to predict the hardenability of low- and high-hardenability steel. Model validation is carried out by calculating and comparing the hardenability curves of five steels using different models. The results reveal that the CML model works well for its distinguished prediction performance with precise classification accuracy (100%), high correlation coefficient (≥0.981), and low mean absolute errors (≤3.6 HRC) and root-mean-square errors (≤3.9 HRC); it performs better than JMatPro and empirical formulas including the ideal critical diameter method and modified nonlinear equation. Therefore, this study demonstrates that the CML model combining material informatics and data-driven machine learning can rapidly and efficiently predict the hardenability curves of non-boron steel, with high prediction accuracy and a wide application range. It can guide process design and machine part selection, reducing the cost of trial and error and accelerating the development of new materials.

Single-crystal two-dimensional material epitaxy on tailored non-single-crystal substrates.

The use of single-crystal substrates as templates for the epitaxial growth of single-crystal overlayers has been a primary principle of materials epitaxy for more than 70 years. Here we report our finding that, though counterintuitive, single-crystal 2D materials can be epitaxially grown on twinned crystals. By establishing a geometric principle to describe 2D materials alignment on high-index surfaces, we show that 2D material islands grown on the two sides of a twin boundary can be well aligned. To validate this prediction, wafer-scale Cu foils with abundant twin boundaries were synthesized, and on the surfaces of these polycrystalline Cu foils, we have successfully grown wafer-scale single-crystal graphene and hexagonal boron nitride films. In addition, to greatly increasing the availability of large area high-quality 2D single crystals, our discovery also extends the fundamental understanding of materials epitaxy.

Contrasting Hydraulic Efficiency and Photosynthesis Strategy in Differential Successional Stages of a Subtropical Forest in a Karst Region.

Understanding the successional process from a disturbed forest to a mature forest is essential for species recovery and conservation initiatives. The resource acquisition and drought tolerance of plants can be instructive to predictions of species abundance and distribution for different forests. However, they have not been adequately tested at different successional stages in karst regions. Here, we selected seven dominant species in an early-succession forest and 17 species in a late-succession forest in a karst region of southwestern China. Resource acquisition-related traits such as hydraulic conductivity and photosynthetic rate, and drought tolerance-related traits, including turgor loss point and wood density, were measured. We found that species in the early-succession forest had a higher hydraulic conductance and photosynthetic rate than those in the late-succession forest, while leaf water potential at turgor loss point and wood density showed nonsignificant differences between the two forests. In addition, we observed a significant negative relationship between photosynthetic rate and drought tolerance in the early-succession forest, which was not identified in late-succession forests. Our study indicates that resource acquisition rather than drought tolerance was the key factor explaining plant distributions in forests at different successional stages in karst regions. We also suggest that the resource acquisition and drought tolerance trade-off hypothesis is not always supported for karst region species. Our study could inform about the design of species replacements in successional forests and provide forest management and restoration guidelines for karst regions.

High Temperature Deformation Behavior and Microstructure Evolution of Low-Density Steel Fe30Mn11Al1C Micro-Alloyed with Nb and V.

The thermal processing parameters is very important to the hot rolling and forging process for producing grain refinement in lightweight high-manganese and aluminum steels. In this work, the high temperature deformation behaviors of a low-density steel of Fe30Mn11Al1C alloyed with 0.1Nb and 0.1V were studied by isothermal hot compression tests at temperatures of 850-1150 °C and strain rates between 0.01 s-1 and 10 s-1. It was found that the flow stress constitutive model could be effectively established by the Arrhenius based hyperbolic sine equation with an activation energy of about 389.1 kJ/mol. The thermal processing maps were developed based on the dynamic material model at different strains. It's shown that the safe region for high temperatures in a very broad range of both deformation temperature and deformation strain and only a small unstable high deformation region, located at low temperatures lower than 950 °C. The deformation microstructures were found to be fully recrystallized microstructure in the safe deformation region and the grain size decreases along with decreasing temperature and increasing strain rate. Whereas the deformation microstructures is composed by grain refinement-recrystallized grains and a small fraction of non-recrystallized microstructure in the unstable deformation region, indicating that the deformation behaviors controlled by continuous dynamic recrystallization. The Hall Petch relationship between microhardness and the grain size of the high temperature deformed materials indicates that high strength low-density steel could be developed by a relative low temperature deformation and high strain rate.

Leaf hydraulic acclimation to nitrogen addition of two dominant tree species in a subtropical forest.

Plant hydraulic traits have been shown to be sensitive to changes in nitrogen (N) availability in short-term studies largely using seedlings or saplings. The extent and the magnitude of N-sensitivity of the field grown mature trees in long-term experiments, however, are relatively unknown. Here, we investigated responses of leaf water relations and morphological and anatomical traits of two dominant tree species (Castanopsis chinensis and Schima superba) to a six-year canopy N addition in a subtropical forest. We found that N addition increased leaf hydraulic conductivity in both species along with higher transpiration rate and less negative water potential at 50% loss of leaf hydraulic conductivity and at leaf turgor loss point. Examination of leaf morphological and anatomical traits revealed that increased leaf hydraulic efficiency was at least in part due to increased vessel diameter which also compromised the hydraulic safety under increased water stress. Moreover, reduced vessel reinforcement and increased thickness shrinkage index further interpreted the increases in leaf hydraulic vulnerability under N addition. Our results demonstrated that N deposition may lead to increases of plant water loss to the atmosphere as well as tree vulnerability to drought.

Removal of gaseous pollutants by using 3DOM-based catalysts: A review.

Catalytic oxidation is a promising technique to control the emission of gaseous pollutants. Three-dimensionally ordered macroporous (3DOM)-based catalysts have aroused widespread attention because of their high porosity, large surface area and pore volume, superb ability of mass transfer. Therefore, they have been widely used in gaseous pollutants control field, such as soot and methane catalytic combustion, VOCs catalytic oxidation, photocatalytic CO2 reduction and so on. In this review, the recent studies about the preparation and applications of 3DOM catalysts are summarized. At the same time, the advantages and mechanism of the 3DOM catalysts used in gaseous pollutants control are introduced in depth. Finally, the perspective and future direction of 3DOM-based catalysts for gaseous pollutants control are proposed.

Enhancement of the activity of Cu/TiO2 catalyst by Eu modification for selective catalytic reduction of NOx with NH3.

The Cu/TiO2 catalysts with the addition of Eu were developed by the sol-gel way for the selective catalytic reduction (SCR) of NOx by NH3. Activity tests revealed that CuEu/TiO2-0.15 catalyst showed the optimal de-NOx performance in a wide temperature range (150-300 °C), along with an admirable SO2 tolerance. According to characterization analysis, the relationship between the NH3-SCR performance and physicochemical characters of samples was explored. The adjunction of Eu on Cu/TiO2 catalyst can contribute to the formation of a large amount of Cu2+, adsorbed oxygen, and acid sites on the catalyst surface. Moreover, the Eu addition on Cu/TiO2 is favorable to the generation of activated NOx and NH3 substances adsorbed on the catalyst surface, which would conduce to the NH3-SCR process by Langmuir-Hinshelwood (L-H) mechanism effectively.

Selective catalytic reduction of NOx by NH3 over CeVO4-CeO2 nanocomposite.

In this study, it was found that the CeVO4-CeO2 nanocomposite possessed remarkably selective catalytic reduction (SCR) performance and wider active temperature scope. And, the promotion principle was explored based on BET, XRD, XPS, H2-temperature-programmed reduction, NH3-temperature-programmed desorption, and in situ diffuse reflectance infrared Fourier transform (DRIFT) techniques. The characterization outcomes manifested that the CeVO4-CeO2 nanocomposite could inhibit its crystallinity and enhance the concentrations of chemisorbed oxygen species and Ce3+, which was advantageous to the SCR process. Moreover, the in situ DRIFT technique manifested that the NH3-SCR reaction over Ce0.75V0.25Oy was enhanced effectively through the mechanism of L-H.